H. Ármannsson, An overview of carbon dioxide emissions from Icelandic geothermal 687 areas, Appl. Geochemistry, vol.97, pp.11-18, 2018.

H. Ármannsson, CO2 emission from geothermal plants, 2003.

. Conference, , pp.56-62

S. Arnórsson, E. Gunnlaugsson, and H. Svavarsson, The chemistry of geothermal waters in, 1983.

. Iceland and . Iii, Chemical geothermometry in geothermal investigations, Geochim

, Cosmochim. Acta, vol.47, pp.90278-90286

I. Arrizabalaga, M. De-gregorio, C. Noceda, R. Hidalgo, and J. F. Urchueguía, Country Update for the Spanish Geothermal Sector, in: World Geothermal Congress 695, vol.694, p.9, 2015.

M. P. Asta, M. J. Gimeno, L. F. Auqué, J. Gómez, P. Acero et al., , 2012.

, Hydrochemistry and geothermometrical modeling of low-temperature Panticosa 698 geothermal system (Spain), J. Volcanol. Geotherm. Res, pp.84-95


L. F. Auqué, P. Acero, M. J. Gimeno, J. B. Gómez, and M. P. Asta, Hydrogeochemical 701 modeling of a thermal system and lessons learned for CO2 geologic storage, Chem. Geol, vol.702, pp.324-336, 2009.

J. M. Azañón and A. Crespo-blanc, Exhumation during a continental collision inferred from 704 the tectonometamorphic evolution of the Alpujarride Complex in the central Betics, SE Spain). Tectonics, vol.705, pp.549-565, 2000.


J. M. Azañón, V. García-dueñas, and B. Goffé, Exhumation of high-pressure metapelites 708 and coeval crustal extension in the Alpujarride complex, 1998.

, Tectonophysics, vol.285, pp.273-277

M. Battistel, S. Hurwitz, W. C. Evans, and M. Barbieri, The chemistry and isotopic 711 composition of waters in the low-enthalpy geothermal system of Cimino-Vico Volcanic 712 District, Italy. J. Volcanol. Geotherm. Res, vol.328, pp.222-229, 2016.


B. Herrera, J. Sanz-de-galdeano, and C. , geothermometry and influence of the concentration of mobile elements in the chemical 721 characteristics of carbonate-evaporitic thermal systems. The case of the Tiermas 722 geothermal system (Spain), Estud. Geológicos, vol.41, pp.696-709, 1985.


M. Blasco, M. J. Gimeno, and L. F. Auqué, Low temperature geothermal systems in 725 carbonate-evaporitic rocks: Mineral equilibria assumptions and geothermometrical 726 calculations. Insights from the Arnedillo thermal waters (Spain), Sci. Total Environ, vol.615, pp.526-539, 2018.

J. C. Braga, J. M. Martín, and C. Quesada, Patterns and average rates of late Neogene, 2003.

, Recent uplift of the Betic Cordillera, SE Spain. Geomorphology, vol.50, pp.3-26

, , pp.205-207

E. Buforn, M. Bezzeghoud, A. Udías, and C. Pro, Seismic Sources on the Iberia-African, 2004.

, Plate Boundary and their Tectonic Implications, Pure Appl. Geophys, vol.161, pp.623-646


J. C. Campos, Guía de manantiales de la provincia de Granada: Una visión sobre su 735 origen y naturaleza, 2006.

G. Capasso, R. Favara, F. Grassa, S. Inguaggiato, and M. Longo, On-line technique for 737 preparing and measuring stable carbon isotope of total dissolved inorganic carbon in water 738 samples (? 13 CTDIC), Ann. Geophys, vol.48, pp.159-166, 2005.

G. Capasso and S. Inguaggiato, A simple method for the determination of dissolved gases 740 in natural waters. An application to thermal waters from Vulcano Island, 1998.

, Geochemistry 13, pp.109-110

F. Capecchiacci, F. Tassi, O. Vaselli, G. Bicocchi, J. Cabassi et al., , p.743

G. Chiocciora, A combined geochemical and isotopic study of the fluids discharged 744 from the Montecatini thermal system, Appl. Geochemistry, vol.59, pp.33-745, 2015.

, Détermination de la silice 747 réactive dans l'eau : méthode par spectrophotométrie UV-visible, 2016.

D. Ranaldi and M. , Carbon dioxide degassing at Latera caldera (Italy): Evidence of 754 geothermal reservoir and evaluation of its potential energy, J. Geophys. Res, vol.112, pp.1-17, 2007.


G. Chiodini, R. Cioni, M. Guidi, B. Raco, and L. Marini, Soil CO2 flux measurements in 757 volcanic and geothermal areas, Appl. Geochemistry, vol.13, pp.543-552, 1998.

G. Chiodini, F. Frondini, and L. Marini, Theoretical geothermometers and PCO2 indicators 759 for aqueous solutions coming from hydrothermal systems of medium-low temperature 760 hosted in carbonate-evaporite rocks, 1995.

. Swell, Italy. Appl. Geochemistry, vol.10, issue.95, pp.6-6

G. Chiodini, F. Frondini, and F. Ponziani, Deep structures and carbon dioxide degassing 764 in Central Italy, Geothermics, vol.24, pp.23-29, 1995.

I. D. Clark and P. Fritz, Environmental isotopes in hydrogeology, 1997.

, Publishers

H. Corbí, C. Lancis, F. García-garcía, J. Pina, J. M. Soria et al., , p.768

C. , Updating the marine biostratigraphy of the Granada Basin (central Betic, 2012.

. Cordillera, Insight for the Late Miocene palaeogeographic evolution of the Atlantic

, Mediterranean seaway, Geobios, vol.45, pp.249-263


A. Coudrain-ribstein, P. Gouze, and G. De-marsily, Temperature-carbon dioxide partial 773 pressure trends in confined aquifers, Chem. Geol, vol.1, pp.73-89, 1998.

, , pp.161-168

J. Cruz-sanjulián, L. G. Rossell, and J. G. Blasco, Aguas termales de la provincia de, 1972.

. Granada and . Bol, Geológico y Min. T.LXXXIII-III, pp.266-275

J. Cruz-sanjulián and J. M. Granda, Temperatura de base de las aguas termales de la 778 provincia de Granada, in: II Simposio Nacional de Hidrogeología, pp.547-568, 1979.

F. D'amore, S. Arnórsson, and S. A. Geothermometry, Isotopic and Chemical Techniques 780 in Geothermal Exploration, Dev. Use Sampl. Methods, Data Handl. Interpret. Int. At, 2000.

F. D'amore, R. Fancelli, and R. Caboi, Observations on the application of chemical 783 geothermometers to some hydrothermal systems in Sardinia, Tectonophysics, vol.16, pp.29-53, 1987.

, , pp.29-37

R. O. Fournier, Chemical geothermometers and mixing models for geothermal systems, 1977.

, Geothermics, vol.5, pp.90007-90011

R. O. Fournier and R. W. Potter, An equation correlating the solubility of quartz in water 793 from 25° to 900°C at pressures up to 10,000 bars, Geochim. Cosmochim. Acta, vol.46, pp.1969-794, 1973.

A. Fusari, M. R. Carroll, S. Ferraro, R. Giovannetti, G. Giudetti et al., , p.796

M. Pennisi, Circulation path of thermal waters within the Laga foredeep basin 797 inferred from chemical and isotopic (?18O, ?D, 3H, 87Sr/86Sr) data, Appl. Geochemistry, vol.798, pp.23-34, 2017.

J. Galindo-zaldívar, A. J. Gil, C. Sanz-de-galdeano, M. C. Lacy, and J. A. García-armenteros, , p.800

P. Ruano, A. M. Ruiz, M. Martínez-martos, and P. Alfaro, Active shallow extension 801 in central and eastern Betic Cordillera from CGPS data, Tectonophysics, vol.663, pp.290-301, 2015.


G. Gran, Determination of the equivalence point in potentiometric titrations, 1952.

, Analyst, vol.77, pp.661-671

M. C. Harvey, J. V. Rowland, G. Chiodini, C. F. Rissmann, S. Bloomberg et al., , p.806

A. A. Oladottir, CO2 flux geothermometer for geothermal exploration, 2017.

, Cosmochim. Acta, vol.213, pp.1-16

T. M. Hunt, Five Lectures on Environmental Effects of Geothermal Utilization, p.809, 2001.

, Geothermal Training Programme

I. A. Hutcheon, M. Shevalier, and H. J. Abercrombie, pH buffering by metastable mineral-811 fluid equilibria and evolution of carbon dioxide fugacity during burial diagenesis, 1993.

, Geochim. Cosmochim. Acta, vol.57, pp.1017-1027

S. Inguaggiato and A. Rizzo, Dissolved helium isotope ratios in ground-waters: a new 814 technique based on gas--water re-equilibration and its application to Stromboli volcanic 815 system, Appl. Geochemistry, vol.19, pp.665-673, 2004.


M. López-chicano, M. Bouamama, A. Vallejos, and A. Pulido-bosch, Factors which 823 determine the hydrogeochemical behaviour of karstic springs, 2001.

S. Cordilleras, Appl. Geochemistry, vol.16, issue.01, pp.12-21

M. López-chicano, J. C. Cerón, A. Vallejos, and A. Pulido-bosch, Geochemistry of 827 thermal springs, Alhama de Granada (southern Spain). Appl. Geochemistry, vol.16, pp.1153-828, 2001.

L. Marini, G. Chiodini, and R. Cioni, New geothermometers for carbonate-evaporite 830 geothermal reservoirs, Geothermics, vol.15, pp.77-86, 1986.

A. Martín-algarra, M. Marti?n-marti?n, B. Andreo, R. Julià, and C. González-gómez, , 2003.

, Sedimentary patterns in perched spring travertines near Granada (Spain) as indicators of 834 the paleohydrological and paleoclimatological evolution of a karst massif, Sediment. Geol, vol.835, issue.161, pp.217-228

J. M. Martín and J. C. Braga, Alpujárride carbonate deposits, 1987.

, Sedimentation in a Triassic Atlantic, Palaeogeogr. Palaeoclimatol. Palaeoecol, vol.59, pp.243-838

A. T. Mccay, M. E. Feliks, and J. J. Roberts, Life cycle assessment of the carbon intensity 840 of deep geothermal heat systems: A case study from Scotland, Sci. Total Environ, vol.685, pp.208-219, 2019.

G. Michard, Behaviour of major elements and some trace elements, p.843, 1990.

W. Mn and F. ). , deep hot waters from granitic areas, Chem. Geol, vol.89, pp.117-134


G. Michard, Géothermomètres chimiques. Bull. BRGM, vol.2, pp.183-189, 1979.

D. L. Parkhurst, C. A. Appelo, and . Others, Description of input and examples for 847 PHREEQC version 3 -a computer program for speciation, batch-reaction, one-848 dimensional transport, and inverse geochemical calculations, US Geol. Surv. Tech, 2013.

, , vol.497

P. Del-villar and L. , Almacenamiento geológico de CO2: Análogos del almacenamiento 851 y escape. Fundamentos, ejemplos y aplicaciones para la predicción de riesgos y la 852 evaluación del comportamiento a largo plazo, Congr. Nac. del Medio Ambient, 2009.

J. D. Rimstidt and H. L. Barnes, The kinetics of silica-water reactions, 1980.

, Cosmochim. Acta, vol.44

J. Rodríguez-fernández and C. Sanz-de-galdeano, Late orogenic intramontane basin 860 development : the Granada basin, Betics (southern Spain). Basin Res, vol.18, pp.85-102, 2006.


J. Sánchez-guzmán and C. García-de-la-noceda, The Evolution of Geothermal Energy in, 2010.

. Spain--country-update, , 2005.

C. Sanz-de-galdeano, The Cadiz-Alicante fault: an important discontinuity in the Betic 865, 2008.

, Cordillera. Rev. la Soc. Geológica España, vol.21

C. Sanz-de-galdeano, Geologic evolution of the Betic Cordilleras in the Western 867, 1990.

. Mediterranean, Miocene to the present, Tectonophysics, vol.172, pp.107-119


C. Sanz-de-galdeano and J. A. Peláez, Fallas activas en la Cordillera Bética: una 870 aproximación a partir de la información tectónica y sísmica, 2011.

. Granada,

C. Sanz-de-galdeano and J. A. Pela?ez, Fallas activas en la Cordillera Bética : una 873 aproximación a partir de la información tectónica y si?smica, 2011.

C. Sanz-de-galdeano and J. A. Vera, Stratigraphic record and palaeogeographical context of 875 the Neogene basins in the Betic Cordillera, Spain. Basin Res, vol.4, pp.21-36, 1992.


T. M. Seward and D. M. Kerrick, Hydrothermal CO2 emission from the Taupo volcanic 878 zone, New Zealand. Earth Planet. Sci. Lett, vol.139, pp.105-113, 1996.

M. P. Tole, H. Ármannsson, P. Zhong-he, and S. Arnórsson, Fluid/mineral equilibrium 880 calculations for geothermal fluids and chemical geothermometry, Geothermics, vol.22, pp.17-37, 1993.

M. P. Verma, Chemical thermodynamics of silica: A critique on its geothermometer, 2000.