D. Gulino, J. Galy, J. P. Pascault, L. Tighzert, and Q. T. Pham, ?tude des pr?polym?res ?poxydes par chromatographie et 1 RMN?350RMN?RMN?350 MHz. Die Makromolekulare Chemie, vol.184, pp.411-429, 1983.

R. B. Prime, Thermosets. In: Thermal Characterization of Polymeric Materials, pp.435-569, 1981.

J. P. Pascault, Chimie et mise en Ïuvre des m?langes r?actifs, InitiationîaInitiationîa chimie etîaetîa physico-chimie macromol?culaire, 7 : mat?riaux composites?basecomposites?composites?base de polym?res, pp.14-41, 1989.

N. A. St-john and G. A. George, Diglycidyl amineepoxy resin networks: kinetics and mechanisms of cure, Progress in Polymer Science, vol.19, pp.755-795, 1994.

B. A. Rozenberg, Kinetics, thermodynamics and mechanisms of reactions of oligomers with amines, Advances in Polymer Science: Epoxy Resins and Composites II, vol.75, pp.113-165, 1986.

X. Wang and J. K. Gillham, Competitive primary amine/epoxy and secondary amine/epoxy reactions: effect on the isothermal time-to-vitrify, Journal of Applied Polymer Science, vol.43, pp.2267-2277, 1991.

R. Lovell, H. Et, and . Windle, WAXS investigation of local structure in epoxy networks, Polymer, vol.31, pp.593-601, 1990.

C. C. Riccardi and R. J. Williams, A kinetic scheme for amine-epoxy reaction with simultaneous etherification, Journal of Applied Polymer Science, vol.32, pp.3445-3456, 1986.

S. A. , T. M. Lam, J. P. Pascault, M. F. Grenier-loustalot, and E. P. Grenier, Characterization and behaviour of epoxy-based diaminodiphenylsulfone networks, Polymer, vol.28, pp.1030-1036, 1987.

S. Cukierman, R. P. Eustache, J. L. Halary, F. Laupr?tre, and L. Monnerie, Processus de d?formation des matrices de composite en relation avec leur structure mol?culaire

R. P. Eustache, ?tude par RMN 13 C haute r?solution dans les solides de la structure chimique des r?sines polyester et de la dynamique mol?culaire dans les r?sines ?poxy et dans les r?sines polyester. Th?se de doctorat de lÕuniversit?, 1990.

J. Galy, A. Sabra, and J. P. Pascault, Characterization of epoxy thermosetting systems by differential scanning calorimetry, Polymer Engineering and Science, vol.26, pp.1514-1523, 1986.

J. K. Gillham, Curing. In: Encyclopedia of Polymer Science and Engineering, vol.4, pp.322-382, 1986.

P. J. Flory, Principles of Polymer Chemistry, 1971.

R. Pétrole, , vol.52, 1997.

X. Peng and J. K. Gillham, Time-Temperature-Transformation (TTT) cure diagrams: relationship between Tg and the temperature and time of cure for epoxy systems, Journal of Applied Polymer Science, vol.30, pp.4685-4696, 1985.

P. Bardonnet, R?sines ?poxydes : mise en Ïuvre et applications, Techniques de lÕing?nieur : trait? des plastiques, vol.3, p.466

A. R. Plepys and R. J. Farris, Evolution of residual stresses in three-dimensionally constrained epoxy resins, Polymer, vol.31, pp.1932-1936, 1990.

D. Bauchi?re, Relation entre les caract?ristiques physiques de r?seaux ?poxy mod?les et le d?veloppement de contraintes internes, 1995.

K. Doesek, Network formation in curing of epoxy resin, Advances in Polymer Science: Epoxy Resins and Composites III, vol.78, pp.1-59, 1986.

E. F. Oleinik, Epoxy-aromatic amine networks in the glassy state: structure and properties, Advances in Polymer Science: Epoxy Resins and Composites IV, vol.80, pp.49-99, 1986.

V. B. Gupta, L. T. Drzal, W. W. Adams, and R. Omlor, An electron microscopic study of the morphology of cured epoxy resin, Journal of Materials Science, vol.20, pp.3439-3452, 1985.

R. J. Morgan, Structure-properties relations of epoxies used as composite matrices, Advances in Polymer Science: Epoxy Resins and Composites I, vol.72, pp.1-43, 1985.

J. Mijovic and J. A. Koutsky, Correlation between nodular morphology and fracture properties of cured epoxy resins, Polymer, vol.20, pp.1095-1107, 1979.

C. S. Wu, Effect of stirring on morphology and properties in a catalyst cured epoxy system, Journal of Applied Polymer Science, vol.43, pp.1421-1429, 1991.

G. Sanz, J. Garmendia, M. A. Andres, and I. Mondragon, Dependence of dynamic mechanical behavior of DGEBA/ DDM stoichiometric epoxy systems on the conditions of curing process, Journal of Applied Polymer Science, vol.55, pp.75-87, 1995.

S. Cukierman, Analyse mol?culaire des relations entre structure chimique et propri?t?s dynamiques m?caniques de r?seaux ?poxy mod?les. Th?se de doctorat de lÕuniversit? Paris VI, 1991.

K. Doesek, J. Plestil, and F. Lednicky, Are cured epoxy resins inhomogeneous? Polymer, vol.19, pp.393-397, 1978.

J. L. Halary, L. Monnerie, F. Laupr?tre, and S. Cukierman, Structure-property relationships in model epoxy networks, Macromolecular Reports, pp.927-934, 1994.

J. F. Gerard, J. Galy, J. P. Pascault, S. Cukierman, and J. L. Halary, Viscoelastic response of model epoxy networks in the glass transition region, Polymer Engineering and Science, vol.31, pp.615-621, 1991.

S. Cukierman, J. L. Halary, and L. Monnerie, Dynamic mechanical response of model epoxy networks in the glassy state, Polymer Engineering and Science, vol.31, pp.1476-1482, 1991.

J. L. Halary, S. Cukierman, and L. Monnerie, Relations entre structure chimique et propri?t?s m?caniques dans les r?seaux ?poxydes. Bulletin de la Soci?t? chimique de Belgique, vol.98, pp.623-634, 1989.

N. D. Danieley and E. R. Long, Effects of curing on the glass transition temperature and moisture absorption of a neat epoxy resin, Journal of Polymer Science, vol.19, pp.2443-2449, 1981.

T. D. Chang, S. H. Carr, and J. O. Brittain, Studies of epoxy resin systems. Part B: Effect of crosslinking on the physical properties of an epoxy resin, Polymer Engineering and Science, vol.22, pp.1213-1220, 1982.

J. D. Lemay and F. N. Kelley, Structure and ultimate properties of epoxy resins, Advances in Polymer Science: Epoxy Resins and Composites III, vol.78, pp.115-148, 1986.

F. Meyer, G. Sanz, A. Eceiza, I. Mondragon, and J. Mijovik, The effect of stoichiometry and thermal history during cure on structure and properties of epoxy network, Polymer, vol.36, pp.1407-1414, 1995.

B. G. Min, J. H. Hodgkin, and Z. H. Stachurski, The dependence of fracture properties on cure temperature in DGEBA/DDS epoxy system, Journal of Applied Polymer Science, vol.48, pp.1303-1312, 1993.

G. Wisanrakkit and J. K. Gillham, The glass transition temperature (Tg) as an index of chemical conversion for a high-Tg amine/epoxy system: chemical and diffusioncontrolled reaction kinetics, Journal of Applied Polymer Science, vol.41, pp.2885-2929, 1990.

T. Murayama and J. P. Bell, Relation between the network structure and dynamic mechanical properties of a typical amine-cured epoxy polymer, Journal of Polymer Science, pp.437-445, 1970.

V. B. Gupta, L. T. Drzal, and C. Y. Lee, The temperature-dependence of some mechanical properties of cured epoxy resin systems, Polymer Engineering and Science, vol.25, pp.872-823, 1985.

V. B. Gupta and L. T. , The physical basis of moisture transport in a cured epoxy resin system, Journal of Applied Polymer Science, vol.30, pp.4467-4493, 1985.

J. D. Lemay, B. J. Swetlin, and F. N. Kelley, Structure and fracture of highly cross-linked networks, ACS Symposium Series, vol.243, pp.165-183, 1984.

F. M. Kong, C. M. Walkup, and R. J. Morgan, The relation between the network structure, deformation and failure processes, and mechanical properties of epoxies, Composites Technology Review, vol.4, pp.88-93, 1982.

R. J. Morgan, C. M. Walkup, F. M. Kong, and E. T. Mones, Development of epoxy matrices for filament-wound graphite structures, 30th National SAMPE Symposium, pp.1209-1220, 1985.

U. M. Vakil and G. C. Martin, Crosslinked epoxies: network structure characterization and physical-mechanical properties, Journal of Applied Polymer Science, vol.46, pp.2089-2099, 1992.
DOI : 10.1002/app.1992.070461204

S. C. Misra, J. A. Manson, and L. H. Sperling, Effect of cross-link density distribution on the engineering behavior of epoxies, Advances in Chemistry Series, vol.114, pp.137-156, 1979.

L. Banks, B. Et, and . Ellis, The glass transition temperatures of highly crosslinked networks: cured epoxy resins, Polymer, vol.23, pp.1466-1472, 1982.

J. D. Lemay, The influence of molecular structure on the mechanical and fracture behavior of highly crosslinked epoxy networks, 1985.

V. Bellenger, E. Morel, and J. Verdu, Structureproperties relationships for densely crosslinked epoxideamine systems based on epoxyde or amine mixtures, Journal of Materials Science, vol.23, pp.4244-4250, 1988.

D. Marzio and E. A. , On the second-order transition of rubber, Journal of Research of the National Bureau of Standard Ð A. Physics and Chemistry, vol.68, pp.611-617, 1964.

T. G. Fox, S. Loshaek, ;. , and R. Pétrole, Influence of molecular weight and degree of crosslinking on the specific volume, vol.52, 1955.

, glass temperature of polymers, Journal of Polymer Science, vol.15, pp.371-390

V. Bellenger, J. Verdu, and E. Morel, Effect of structure on glass transition temperature of amine crosslinked epoxies, Journal of Polymer Science. Part B: Polymer Physics, vol.25, pp.1219-1234, 1987.

F. R. Dammont and T. K. Kwei, Dynamic mechanical properties of aromatic, aliphatique, and partially fluorinated epoxy resins, Journal of Polymer Science. Part A, vol.2, pp.761-769, 1967.

J. M. Charlesworth, Effect of crosslink density on the molecular relaxations in diepoxide-diamine network polymers. Part 1: the glassy region, Polymer Engineering and Science, vol.28, pp.221-229, 1988.

M. Ochi, M. Okazaki, and M. Shimbo, Mechanical relaxation mechanism of epoxide resins cured with aliphatic diamines, Journal of Polymer Science. Polymer Physics Edition, vol.20, pp.689-699, 1982.

L. Monnerie, Dynamique locale des polym?res et influence sur les propri?t?s m?caniques, InitiationîaInitiationîa chimie etîaetîa physico-chimie macromol?culaires, vol.8, pp.183-232, 1990.

J. Daly, A. Brittenet, and A. Garton, An additive for increasing the strength and modulus of amine-cured epoxy resins, Journal of Applied Polymer Science, vol.29, pp.1403-1414, 1984.

X. Caux, G. Coulon, and B. Escaig, Influence of the degree of crosslinking on the plastic deformation behaviour of epoxy resins, Polymer, vol.29, pp.808-813, 1988.

E. Espuche, J. Galy, J. F. G?rard, J. P. Pascault, and H. Sautereau, Influence of crosslinked density and chain flexibility on mechanical properties of model epoxy networks, Macromolecular Symposia, vol.93, pp.107-115, 1995.

E. Espuche, J. Galy, J. F. G?rard, J. P. Pascault, and H. Sautereau, Influence de la densit? de r?ticulation et de la flexibilit? des cha"nes sur les propri?t?s m?caniques de r?seaux ?poxydes mod?les. La Revue de M?tallurgie-CIT/ Science et g?nie des mat?riaux, pp.1017-1026, 1995.

J. L. Halary, S. Cukierman, and L. Monnerie, Annales des composites : Composites?matriceComposites?Composites?matrice polym?re et humidit?, AMAC, pp.103-112, 1992.

J. B. Enns and J. K. Gillham, Effect of the extent of cure on the modulus, glass transition, water absorption, and density of an amine-cured epoxy, Journal of Applied Polymer Science, vol.28, pp.2831-2846, 1983.

K. P. Pang and J. K. Gillham, Anomalous behavior of cured epoxy resins: Density at room temperature versus time and temperature of cure, Journal of Applied Polymer Science, vol.37, pp.1969-1991, 1989.

X. Wang and J. K. Gillham, Tg-temperature property (Tg-Tp) diagram for thermosetting systems: anomalous behavior of physical properties vs. extent of cure, Journal of Applied Polymer Science, vol.47, pp.425-446, 1993.

R. A. Venditti, J. K. Gillham, Y. C. Jean, and Y. Lou, Free volume after cure vs. fractional conversion for a highTg epoxy/amine thermosetting system, Journal of Applied Polymer Science, vol.56, pp.1207-1220, 1995.
DOI : 10.1002/app.1995.070561003

M. T. Aronhime, X. Peng, and J. K. Gillham, Effect of time-temperature path of cure on the water absorption of high Tg epoxy resins, Journal of Applied Polymer Science, vol.32, pp.3589-3626, 1986.

E. S. Kong, Physical aging in epoxy matrices and composites, Advances in Polymer Science: Epoxy resins and composites IV, vol.80, pp.125-171, 1986.

V. B. Gupta, L. T. Drazl, C. Y. Lee, and M. J. Rich, The effect of stoichiometry and structure on the dynamic torsional properties of a cured epoxy resin system, Journal of Macromolecular Science, vol.23, pp.435-466, 1985.

R. A. Venditti, J. K. Gillham, Y. C. Jean, and Y. Lou, Macroscopic volume, van der waals volume and free volume after cure versus chemical conversion for a high-tg epoxy/amine thermosetting system, Journal of Coatings Technology, vol.67, pp.47-56, 1995.

J. Daly, A. Britten, and A. Garton, An additive for increasing the strength and modulus of amine-cured epoxy resins, Journal of Applied Polymer Science, vol.29, pp.1403-1414, 1984.

R. Pétrole, , vol.52, 1997.