Fischer-Tropsch Synthesis: Development of a Microkinetic Model for Metal Catalysis

Abstract : The construction of a single-event microkinetic (SEMK) model for metal catalysis using Fischer-Tropsch synthesis as example reaction is addressed. SEMK's describe the full product distribution with a limited number of kinetic parameters. A computer algorithm is required to generate all the elementary steps and species of the reaction network. Reacting and intermediate species are represented with Boolean matrices and standardized labels. The adjustable model parameters are the atomic chemisorption enthalpies of carbon, oxygen and hydrogen on the metal surface and the single-event kinetic coefficients of the kinetically relevant reaction families.
Document type :
Journal articles
Complete list of metadatas

Cited literature [30 references]  Display  Hide  Download

https://hal-ifp.archives-ouvertes.fr/hal-02005854
Contributor : Edp Sciences <>
Submitted on : Monday, February 4, 2019 - 11:46:04 AM
Last modification on : Thursday, February 7, 2019 - 5:52:30 PM
Long-term archiving on : Sunday, May 5, 2019 - 3:30:05 PM

File

ogst06012.pdf
Publication funded by an institution

Identifiers

Collections

IFP | OGST

Citation

G. Lozano-Blanco, J. W. Thybaut, K. Surla, P. Galtier, G. B. Marin. Fischer-Tropsch Synthesis: Development of a Microkinetic Model for Metal Catalysis. Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles, Institut Français du Pétrole, 2006, 61 (4), pp.489-496. ⟨10.2516/ogst:2006026a⟩. ⟨hal-02005854⟩

Share

Metrics

Record views

11

Files downloads

9