Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst

L. Magna 1, * S. Harry 1 D. Proriol 1 L. Saussine 1 H. Olivier-Bourbigou 1
* Corresponding author
1 IFPEN - IFP Energies nouvelles
Abstract : Hydroformylation of olefins has been performed with a system based on cobalt and pyridine ligands in non-aqueous ionic liquids. In this work, a new approach was developed to recycle the cobalt catalyst without the use of chemicals. For 1-hexene, activity of the [ Co2(CO)8] /Pyridine(2 eq)/[BMIM][ NTf2] at 100 bar and 130°C can reach 110 h-1 with a selectivity for aldehydes of up to 87% (linear to branched ratio being around 1.8). The recycling of the ionic liquid phase was performed several times without loss of activity or selectivity.
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L. Magna, S. Harry, D. Proriol, L. Saussine, H. Olivier-Bourbigou. Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst. Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles, Institut Français du Pétrole, 2007, 62 (6), pp.775-780. ⟨10.2516/ogst:2007052⟩. ⟨hal-02005769⟩

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