Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst - Archive ouverte HAL Access content directly
Journal Articles Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles Year : 2007

Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst

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1
L. Magna
  • Function : Correspondent author
S. Harry
  • Function : Author

Abstract

Hydroformylation of olefins has been performed with a system based on cobalt and pyridine ligands in non-aqueous ionic liquids. In this work, a new approach was developed to recycle the cobalt catalyst without the use of chemicals. For 1-hexene, activity of the [ Co2(CO)8] /Pyridine(2 eq)/[BMIM][ NTf2] at 100 bar and 130°C can reach 110 h-1 with a selectivity for aldehydes of up to 87% (linear to branched ratio being around 1.8). The recycling of the ionic liquid phase was performed several times without loss of activity or selectivity.
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hal-02005769 , version 1 (04-02-2019)

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L. Magna, S. Harry, D. Proriol, L. Saussine, H. Olivier-Bourbigou. Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst. Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles, 2007, 62 (6), pp.775-780. ⟨10.2516/ogst:2007052⟩. ⟨hal-02005769⟩

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