Transformation of Sorbitol to Biofuels by Heterogeneous Catalysis: Chemical and Industrial Considerations

Abstract : Decreasing oil supplies and increasing energy demand provide incentives to find alternative fuels. First, the valorisation of edible crops for ethanol and biodiesel production led to first generation biofuels. Nowadays, research is focused on lignocellulosic biomass as a source of renewable carbon (second generation biofuels). Whereas the cellulosic ethanol production is in progress, a new way consisting of the transformation of ex-lignocellulose sugars and polyols towards light hydrocarbons by heterogeneous catalysis in aqueous phase has been recently described.This process is performed under mild conditions (T < 300 °C and P < 50 bar). It requires on one hand hydrogen formation by catalytic reforming of carbohydrates in aqueous phase and on the other hand, the dehydration/hydrogenation of polyols leading to alkanes by selective C-O bond cleavages. The challenge here is to conceive multifunctional catalytic systems that are stable, active and selective under the reaction conditions.The aim of this article is to present the involved reactions, the catalytic systems described in literature for that kind of transformation and examples of industrial applications.
Document type :
Journal articles
Complete list of metadatas

Cited literature [131 references]  Display  Hide  Download

https://hal-ifp.archives-ouvertes.fr/hal-01936220
Contributor : Edp Sciences <>
Submitted on : Tuesday, November 27, 2018 - 12:11:01 PM
Last modification on : Thursday, February 7, 2019 - 4:29:58 PM
Long-term archiving on : Thursday, February 28, 2019 - 2:01:15 PM

File

ogst120142.pdf
Publication funded by an institution

Identifiers

Collections

Citation

Lea Vilcocq, A. Cabiac, C. Especel, E. Guillon, D. Duprez. Transformation of Sorbitol to Biofuels by Heterogeneous Catalysis: Chemical and Industrial Considerations. Oil & Gas Science and Technology - Revue d'IFP Energies nouvelles, Institut Français du Pétrole, 2013, 68 (5), pp.841-860. ⟨10.2516/ogst/2012073⟩. ⟨hal-01936220⟩

Share

Metrics

Record views

39

Files downloads

108