Quantification of metal-acid balance in hydroisomerization catalysts: A step further toward catalyst design

Pedro S. F. Mendes; João M. Silva; M. Filipa Ribeiro; Pascal Duchêne; Antoine Daudin; Christophe Bouchy

doi:10.1002/aic.15613

Quantification of metal-acid balance in hydroisomerization catalysts: A step further toward catalyst design

Pedro S. F. Mendes ^{1, 2} João M. Silva ^{3, 1} M. Filipa Ribeiro ¹ Pascal Duchêne ² Antoine Daudin ² Christophe Bouchy ^{2, *}

* Auteur correspondant

1 Instituto Superior Técnico

2 IFPEN - IFP Energies nouvelles

3 Instituto Politécnico de Lisboa

Abstract : A methodology was developed to interpret the results of n-paraffins hydroisomerization over bifunctional catalysts based on two simple kinetic models used consecutively. Firstly, a macrokinetic model was used to obtain the corresponding turnover frequency over the acid sites and the maximum of C 16 isomer yield. Secondly, a dual-function model was used to correlate these catalytic descriptors to the ratio of metal to acid sites of the catalyst. To illustrate the methodology, Pt/HBEA and Pt/HUSY catalysts with different Pt loadings were evaluated. The impact of metal-acid balance on the catalytic turnover frequency and the maximal C 16 isomer yield were adequately captured for the bifunctional HUSY and HBEA catalysts. Moreover, the parameters of the dual-function model revealed to be intrinsic to the catalytic properties of the zeolite under the scope. This methodology is believed to be of interest for information-driven catalyst design for the hydroisomerization of n-paraffins.

Keywords : hydroisomerization kinetic model metal-acid balance zeolite High- Throughput Experimentation

Type de document :

Article dans une revue

AIChE Journal, Wiley, 2017, 63 (7), pp.2864 - 2875. 〈10.1002/aic.15613〉

Domaine :

Chimie / Catalyse

Chimie

Liste complète des métadonnées

https://hal-ifp.archives-ouvertes.fr/hal-01581867
Contributeur : Françoise Bertrand <>
Soumis le : mardi 5 septembre 2017 - 11:37:23
Dernière modification le : mardi 15 mai 2018 - 14:50:03

Quantification of metal-acid balance in hydroisomerization catalysts: A step further toward catalyst design

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Quantification of metal-acid balance in hydroisomerization catalysts: A step further toward catalyst design

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