 |
Journal articles
Kinetics of Carbon Dioxide with Amines. I. Stopped-Flow Studies in Aqueous Solutions. A Review
Abstract : It is possible to find plenty of information about kinetics of reaction between amine and carbone dioxide in the literature. However, there are several experimental techniques and several possible mechanisms which lead to observe sometimes high dispersion of experimental results with various interpretations. A method which enables to compare kinetic constant got by different authors is proposed in this work. First, we present experimental techniques and justify comparison of data obtained by stopped-flow technique. Then, we plot kinetic data for all amines studied in the literature by a power law dependency with the concentration. This representation illustrates some structure-activity relationships and enables to confront experimental results with the different mechanisms. Advantages and limits of each mechanism are discussed. Finally, we justify the choice of the termo-lecular model to compare data got by different authors. This model leads to a compensation effect which is an argument in favour of this mechanism.
Cited literature [60 references]
https://hal-ifp.archives-ouvertes.fr/hal-01085331
Contributor : Françoise Bertrand Connect in order to contact the contributor
Submitted on : Friday, November 21, 2014 - 11:17:22 AM
Last modification on : Monday, March 28, 2022 - 11:26:04 AM
Long-term archiving on: : Friday, April 14, 2017 - 7:18:17 PM
Contributor : Françoise Bertrand Connect in order to contact the contributor
Submitted on : Friday, November 21, 2014 - 11:17:22 AM
Last modification on : Monday, March 28, 2022 - 11:26:04 AM
Long-term archiving on: : Friday, April 14, 2017 - 7:18:17 PM
File
A9RCBC3.pdf
Publisher files allowed on an open archive