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Journal articles
Cycloalkyl-based unsymmetrical unsaturated (U2)-NHC ligands : flexibility and dissymmetry in ruthenium-catalysed olefin metathesis.
Abstract : Air-stable Ru-indenylidene and Hoveyda-type complexes bearing new unsymmetrical unsaturated N-heterocyclic carbene (U2-NHC) ligands combining a mesityl unit and a flexible cycloalkyl moiety as N-substituents were synthesised. Structural features, chemical stabilities and catalytic profiles in olefin metathesis of this new library of cycloalkyl-based U2-NHC Ru complexes were studied and compared with their unsymmetrical saturated NHC-Ru homologues as well as a set of commercially available Ru-catalysts bearing either symmetrical SIMes or IMes NHC ligands.
Cited literature [9 references]
https://hal-ifp.archives-ouvertes.fr/hal-01068360
Contributor : Françoise Bertrand <>
Submitted on : Friday, December 18, 2015 - 3:19:04 PM
Last modification on : Thursday, March 5, 2020 - 2:06:40 PM
Document(s) archivé(s) le : Saturday, March 19, 2016 - 2:10:13 PM
Contributor : Françoise Bertrand <>
Submitted on : Friday, December 18, 2015 - 3:19:04 PM
Last modification on : Thursday, March 5, 2020 - 2:06:40 PM
Document(s) archivé(s) le : Saturday, March 19, 2016 - 2:10:13 PM
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