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Journal articles
Immobilization of a Full Photosystem in the Large-Pore MIL-101 Metal-Organic Framework for CO2 reduction
Abstract : A molecular catalyst [Cp*Rh(4,4′‐bpydc)]2+ and a molecular photosensitizer [Ru(bpy)2(4,4′‐bpydc)]2+ (bpydc=bipyridinedicarboxylic acid) were co‐immobilized into the highly porous metal–organic framework MIL‐101‐NH2(Al) upon easy postsynthetic impregnation. The Rh–Ru@MIL‐101‐NH2 composite allows the reduction of CO2 under visible light, while exhibiting remarkable selectivity with the exclusive production of formate. This Rh–Ru@MIL‐101‐NH2 solid represents the first example of MOFs functionalized with both a catalyst and a photosensitizer in a noncovalent fashion. Thanks to the coconfinement of the catalyst and photosensitizer into the cavity's nanospace, the MOF pores are used as nanoreactors and enable molecular catalysis in a heterogeneous manner.
Cited literature [42 references]
https://hal.archives-ouvertes.fr/hal-01886655
Contributor : Productionsscientifiques Ircelyon <>
Submitted on : Thursday, July 30, 2020 - 11:49:18 AM
Last modification on : Thursday, January 7, 2021 - 4:36:05 PM
Long-term archiving on: : Tuesday, December 1, 2020 - 7:47:59 PM
Contributor : Productionsscientifiques Ircelyon <>
Submitted on : Thursday, July 30, 2020 - 11:49:18 AM
Last modification on : Thursday, January 7, 2021 - 4:36:05 PM
Long-term archiving on: : Tuesday, December 1, 2020 - 7:47:59 PM
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