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Additional retardation in RAFT polymerization: Detection of terminated intermediate radicals

Abstract : An over-retardation epiphenomenon has been observed during RAFT polymerization of N-acryloylmorpholine mediated by several bio-functional dithioesters. This epiphenomenon has been related to termination reactions onto intermediate radicals. The resulting three-arm species have been observed for the first time in RAFT polymerization conditions by MALDI-TOF mass spectrometry.
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https://hal.archives-ouvertes.fr/hal-01877425
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Submitted on : Wednesday, November 18, 2020 - 2:10:39 PM
Last modification on : Friday, September 10, 2021 - 2:52:01 PM
Long-term archiving on: : Friday, February 19, 2021 - 7:43:12 PM

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Mael Bathfield, Franck d'Agosto, Roger Spitz, Catherine Ladaviere, Marie-Therese Charreyre, et al.. Additional retardation in RAFT polymerization: Detection of terminated intermediate radicals. Macromolecular Rapid Communications, Wiley-VCH Verlag, 2007, 28 (7), pp.856-862. ⟨10.1002/marc.200600861⟩. ⟨hal-01877425⟩

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