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Design and synthesis of 3, 5- hetero diesters of 4-deoxy quinic acid and their aphicidal activity against Acyrthosiphon pisum

Abstract : our analogs of 3,5-dicaffeoylquinic acid, including a new heterodiester of 4-deoxyquinic acid, were found toxic against the pea aphid. Several 4-deoxy quinic analogs featuring two different hydroxyl cinnamoyl moieties in position 3 and 5 were prepared for the first time and carefully analysed. Through an assay on pea aphid nymphs, interesting indications on the structure-aphicidal activity relationships and higher levels of toxicity were observed for four compounds related to the reference natural compound.
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https://hal.archives-ouvertes.fr/hal-03126097
Contributor : Yvan Rahbé <>
Submitted on : Tuesday, June 1, 2021 - 10:21:38 AM
Last modification on : Tuesday, September 14, 2021 - 3:40:20 PM
Long-term archiving on: : Thursday, September 2, 2021 - 6:19:12 PM

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Xiubin Li, Catherine Sivignon, Pedro da Silva, Yvan Rahbé, Yves Queneau, et al.. Design and synthesis of 3, 5- hetero diesters of 4-deoxy quinic acid and their aphicidal activity against Acyrthosiphon pisum. Tetrahedron, Elsevier, 2021, pp.131982. ⟨10.1016/j.tet.2021.131982⟩. ⟨hal-03126097⟩

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